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Please use this identifier to cite or link to this item: http://dspace.utalca.cl/handle/1950/4879

Title: tri-n-butyltin hydride-mediated radical reaction of a 2-iodobenzamide: Formation of an unexpected carbon-tin bond
Authors: Oliveira, M.T.
Prado, M.A.F.
Alves, R.B.
Cesar, A.
Alves, R.J.
Queiroga, C.G.
Santos, L.S.
Eberlin, M.N.
Keywords: tetraorganotin, arylstannane, aryl radical cyclization, 2-iodobenzamide
Issue Date: 2007
Publisher: Sociedade Brasileira de Química
Citation: Journal of the Brazilian Chemical Society 18 (2): 364 - 369
Abstract: The tri-n-butyltin hydride-mediated reaction of methyl 2,3-di-O-benzyl-4-O-trans-cinnamyl -6-deoxy-6-(2-iodobenzoylamino)-a-D-galactopyranoside afforded an unexpected aryltributyltin compound. The structure of this new tetraorganotin(IV) product has been elucidated by 1H, 13C NMR spectroscopy, COSY and HMQC experiments and electrospray ionization mass spectrometry (ESI-MS). The formation of this new compound via a radical coupling reaction and a radical addition-elimination process is discussed
Description: Leonardo S. Santos. Instituto de Química de Recursos Naturales, Universidad de Talca, P.O. Box 747, Talca - Chile.
URI: http://dspace.utalca.cl/handle/1950/4879
ISSN: 0103-5053
Appears in Collections:Artículos en publicaciones ISI - Universidad de Talca

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