DSpace About DSpace Software
 

DSpace Biblioteca Universidad de Talca (v1.5.2) >
Dirección de Programas de Investigación y Asistencia Técnica (DIAT) >
Artículos en publicaciones ISI - Universidad de Talca >

Please use this identifier to cite or link to this item: http://dspace.utalca.cl/handle/1950/9088

Title: Absolute Configuration and H-1 NMR Characterization of Rosmaridiphenol Diacetate
Authors: Munoz, M.A.
Perez-Hernandez, N.
Pertino, M.W.
Schmeda-Hirschmann, G.
Joseph-Nathan, P.
Issue Date: Apr-2012
Publisher: AMER CHEMICAL SOC, 1155 16TH ST, NW, WASHINGTON, DC 20036 USA
Citation: JOURNAL OF NATURAL PRODUCTS Volume: 75 Issue: 4 Pages: 779-783 DOI: 10.1021/np200951y
Abstract: The correction of patented structure 1 of rosmaridiphenol, an antioxidant isolated from rosemary, Rosmarinus officinalis, was made recently. The correct structure is proposed as 11,12-dihydroxy-8,11,13-icetexatrien-l-one (2a) based on 2D NMR data. In order to further support the structure, this work reports the single-crystal X-ray analysis, the complete H-1 NMR assignment by full spin-spin simulation, and the absolute configuration of the diacetate 2b derived via vibrational circular dicroism measurements in comparison with density functional theory calculated data.
Description: Univ Talca, Inst Quim Recursos Nat, Talca, Chile
URI: http://dspace.utalca.cl/handle/1950/9088
ISSN: 0163-3864
Appears in Collections:Artículos en publicaciones ISI - Universidad de Talca

Files in This Item:

File Description SizeFormat
TEXTO_COMPLETO.htmlACCESO RESTRINGIDO RED UTALCA3 kBHTMLView/Open

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

 

Valid XHTML 1.0! DSpace Software Copyright © 2002-2009  The DSpace Foundation - Feedback